Stabilization of Fe/Cu nanoparticles by starch and efficiency of arsenic adsorption from aqueous solutions

Due to the severity of arsenic contamination of soil and water resources around the world, finding new adsorbents for arsenic removal from the water is of high importance. The present study investigates the possible use and effectiveness of starch-stabilized Fe/Cu nanoparticles for adsorption of arsenic from aqueous solutions. First, Fe/Cu nanoparticles at various starch concentrations of 0, 0.02, 0.04 and 0.06 wt% were synthesized and characterized by X-ray diffraction, transmission electron microscopy and zeta potential/particle size analyzer. Then 0.04 wt% stabilized Fe/Cu nanoparticles were tested for the sorption of As(III) and As(V) from synthetic arsenic-contaminated water. To have an understanding about the arsenic adsorption mechanism of nanoparticles, X-ray photoelectron spectroscopy (XPS) was performed before and after adsorption. The results showed that starch provides nanoparticles with a neutral surface and stabilization of nanoparticles is possible with 0.04 wt% or higher concentrations of starch. For 0.04 wt% starch-stabilized Fe/Cu nanoparticles, the adsorption isotherms fit well within the Langmuir equation, with maximum sorption capacities of 90.1 mg/g for As(III) and 126.58 mg/g for As(V) at a pH of 7.0 from the aqueous arsenic solutions. Examining the XPS spectra of nanoparticles before and after adsorption showed that arsenic adsorption by this nanoparticle can be due to the formation of inner-sphere arsenic complexes on the particle surface, and the surface oxygen-containing functional groups involved in adsorption. The high sorption capacity suggests the potential for applying starch-stabilized Fe/Cu nanoparticles to the contaminated waters for removal of arsenic.     

Evaluating qualitative research: dealing with the tension between 'science' and 'creativity'

Summary This paper responds to recent calls for detailed evaluative criteria for qualitative research in human geography. It argues that the dualism between 'science' and 'creativity' is unfounded, and that while systematic methods of evaluation are required, standardization is inappropriate. Furthermore, it seeks to demonstrate that grounded theory provides an alternative framework that demonstrates how these ideas might be put into practice.     

Ascent and eruption of a lunar high-titanium magma as inferred from the petrology of the 74001/2 drill core

Abstract— An analysis of the orange glasses and crystallized beads from the 68 cm deep 74001/2 core has been conducted to understand the processes occurring during ascent and eruption of the Apollo 17 orange glass magma. Equilibrium between melt and metal blebs (Fe₈₅Ni₁₄Co₁) within the core, along with Cr contents in olivine phenocrysts, suggest there was an oxidation of C and a reduction of the melt at an O fugacity of IW-1.3 and 1320 °C to form CO gas at 200 bars or ～4 km depth. This was followed by development of more oxidized conditions during ascent. Also during ascent, there was formation of euhedral, homogeneous Fo₈₁ olivine crystals and spinel crystals with higher Al and Mg contents than the smaller spinels in the crystallized beads. Both the metal blebs and Al-rich spinels were trapped inside the Fo₈₁ olivine phenocrysts as they grew prior to eruption. The composition of the orange glasses are homogeneous throughout the core, except for a few distinct glasses at the top that appear to have been mixed in by micrometeorite reworking. A few glassy melt inclusions of orange glass composition trapped in the Fo₈₁ phenocrysts contain 600 ± 100 ppm S and ～50 ppm Cl compared to the 200 ppm S and 50 ppm Cl in the orange glass melt when quenched. These inclusions therefore document the addition of 400 ppm S to the CO-rich volcanic gas during the eruption. The size and distribution of different volcanic beads in the Apollo 17 deposit indicate a mode of eruption in which the orange glasses and partially crystallized beads formed further away from the volcanic vent where cooling rates were faster. Progressively larger and more numerous crystals in the black beads reflect slower cooling rates at higher optical densities in the volcanic plume. The development of a brown texture in the orange glasses at the bottom of the core, where the black beads dominate, is interpreted to result from devitrification by subsolidus heating either as the orange glasses fell back through the hot plume or after deposition on the surface. The change from domination by orange glasses to black beads in the core probably reflects a decrease in gas content over time, which consequently would increase the plume optical density and favor slower cooling rates.     

Extension et sédimentation au paléozoïque terminal et au Mésozoïque dans le bassin de Majunga (Nord-Ouest de Madagascar)

The Majunga Basin is located in the northwestern part of Madagascar with a N45–60°E trending axis. It was filled by almost exclusively continental Karoo Supergroup sediments, which are Permian to Early Jurassic in age, and by younger sequences, mainly marine, that were deposited from the Middle Jurassic to the present.The Karoo Basin geometry is deduced from the analysis of seismic sections. A central northeast trending horst is flanked by two sub-basins. Deposition of the Karoo sequences was controlled by these northeast trending faults. On the contrary, the Middle Jurassic to present sequences witness only a slight tilting of the basement towards the northwest.The development of the Majunga Basin includes, therefore, two successive stages. In the synrift episode, from Permian to Early Jurassic times, the sedimentation was syntectonic, controlled by synsedimentary faulting and the creation of a horst and graben extensive pattern. The postrift episode started during the Middle Jurassic.These two stages of the Majunga Basin development correspond to the geodynamic evolution recorded elsewhere in this part of the Gondwana.     

New coring study in Augusta Bay expands understanding of offshore tsunami deposits (Eastern Sicily,Italy)

Tsunami deposits present an important archive for understanding tsunami histories and dynamics. Most research in this field has focused on onshore preserved remains, while the offshore deposits have received less attention. In 2009, during a coring campaign with the Italian Navy Magnaghi, four 1 m long gravity cores (MG cores) were sampled from the northern part of Augusta Bay, along a transect in 60 to 110 m water depth. These cores were taken in the same area where a core (MS06) was collected in 2007 about 2·3 km offshore Augusta at a water depth of 72 m below sea level. Core MS06 consisted of a 6·7 m long sequence that included 12 anomalous intervals interpreted as the primary effect of tsunami backwash waves in the last 4500 years. In this study, tsunami deposits were identified, based on sedimentology and displaced benthic foraminifera (as for core MS06) reinforced by X-ray fluorescence data. Two erosional surfaces (L1 and L2) were recognized coupled with grain-size increase, abundant Posidonia oceanica seagrass remains and a significant amount of Nubecularia lucifuga, an epiphytic sessile benthic foraminifera considered to be transported from the inner shelf. The occurrence of Ti/Ca and Ti/Sr increments, coinciding with peaks in organic matter (Mo incoherent/coherent) suggests terrestrial run-off coupled with an input of organic matter. The L1 and L2 horizons were attributed to two distinct historical tsunamis (ad 1542 and ad 1693) by indirect age-estimation methods using ²¹⁰Pb profiles and the comparison of Volume Magnetic Susceptibility data between MG cores and MS06 cores. One most recent bioturbated horizon (Bh), despite not matching the above listed interpretative features, recorded an important palaeoenvironmental change that may correspond to the ad 1908 tsunami. These findings reinforce the value of offshore sediment records as an underutilized resource for the identification of past tsunamis.     

The sediment-fill of Pago Pago Bay (Tutuila Island,American Samoa): New insights on the sediment record of past tsunamis

Extensive bathymetric and two-dimensional seismic surveys have been carried out and cores collected in Pago Pago Bay (Tutuila, American Samoa) in order to describe and gain a better understanding of the sediment fill of the bay, which was affected by the 2009 South Pacific Tsunami. Eight sedimentary units were identified over the volcanic bedrock. The basal transgressive unit displays retrograding onlaps towards the shore, whereas the overlying seven aggradational layers alternate between four draping units and three pinching out seaward units. ‘Core to seismic’ correlation reveals that draping units are composed of homogeneous silts, while pinching out units are dominated by very coarse coral fragments showing fresh cuts, mixed with Halimeda plates. The basal unit is attributed to transgressive sedimentation in response to flooding of the bay after the last glacial maximum, followed by the upper aggradational units corresponding to highstand sedimentation. The changeovers in these upper units indicate an alternation between low-energy silt units and high-energy coral debris units interpreted as tsunami-induced deposits. The ¹⁴C dating reveals that high-energy sedimentation units can last up to approximately 2000 years while low-energy sedimentation units can last up to approximately 1000 years. This alternation, deposited during the last highstand, may be explained by cycles of tectonic activity and quiescence of the Tonga Trench subduction, which is the main source of tsunamigenic earthquakes impacting the Samoan archipelago. In the uppermost silt unit, only the geochemical signature of the terrestrial input of the 2009 SPT backwash deposits was detected between 7 cm and 9 cm depth. Hence, Pago Pago Bay offers a unique sediment record of Holocene bay-fill under the impact of past tsunamis intermittently during the last 7000 years.     

An automated cross‐validation method to assess seismic time‐to‐depth conversion accuracy: a case study on the Cooper and Eromanga basins,Australia

Selecting a seismic time‐to‐depth conversion method can be a subjective choice that is made by geophysicists, and is particularly difficult if the accuracy of these methods is unknown. This study presents an automated statistical approach for assessing seismic time‐to‐depth conversion accuracy by integrating the cross‐validation method with four commonly used seismic time‐to‐depth conversion methods. To showcase this automated approach, we use a regional dataset from the Cooper and Eromanga basins, Australia, consisting of 13 three‐dimensional (3D) seismic surveys, 73 two‐way‐time surface grids and 729 wells. Approximately 10,000 error values (predicted depth vs. measured well depth) and associated variables were calculated. The average velocity method was the most accurate overall (7.6 m mean error); however, the most accurate method and the expected error changed by several metres depending on the combination and value of the most significant variables. Cluster analysis tested the significance of the associated variables to find that the seismic survey location (potentially related to local geology (i.e. sedimentology, structural geology, cementation, pore pressure, etc.), processing workflow, or seismic vintage), formation (potentially associated with reduced signal‐to‐noise with increasing depth or the changes in lithology), distance to the nearest well control, and the spatial location of the predicted well relative to the existing well data envelope had the largest impact on accuracy. Importantly, the effect of these significant variables on accuracy were found to be more important than choosing between the four methods, highlighting the importance of better understanding seismic time‐to‐depth conversions, which can be achieved by applying this automated cross‐validation method.